Transition-Metal-Free Arylations via Photogenerated Triplet 4-Alkyl and 4-Trimethylsilylphenyl Cations

Please use this identifier to cite or link to this item: http://repository.aaup.edu/jspui/handle/123456789/109

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DC Field	Value	Language
dc.contributor.author	hisham qrareya, $AAUP$Palestinian	-
dc.contributor.author	carlotta raviola, $Other$Other	-
dc.contributor.author	stefano protti, $Other$Other	-
dc.contributor.author	maurizio fagnoni, $Other$Other	-
dc.contributor.author	angelo albini., $Other$Other	-
dc.date.accessioned	2019-12-30T07:30:11Z	-
dc.date.available	2019-12-30T07:30:11Z	-
dc.date.issued	2013	-
dc.identifier.uri	http://repository.aaup.edu/jspui/handle/123456789/109	-
dc.description.abstract	The irradiation in protic solvents of 4-chloroalkylbenzenes and 4-chlorophenyltrimethylsilane caused the heterolytic cleavage of aryl?chlorine bonds to give the corresponding triplet phenyl cations. These were exploited for transitionmetal-free arylation reactions under mild conditions to give allylbenzenes, ?-benzyl lactones, 3-arylacetals (ketals), and biaryls in moderate to good yields. The path followed was supported by DFT calculations at the UB3LYP/6-311+G(2d,p) level.	en_US
dc.publisher	The Journal of Organic Chemistry (JOC).	en_US
dc.subject	triplet phenyl cations	en_US
dc.subject	?-benzyl lactones	en_US
dc.subject	transitionmetal-free arylation	en_US
dc.subject	DFT	en_US
dc.title	Transition-Metal-Free Arylations via Photogenerated Triplet 4-Alkyl and 4-Trimethylsilylphenyl Cations	en_US
dc.type	Article	en_US
Appears in Collections:	Faculty & Staff Scientific Research publications

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