Please use this identifier to cite or link to this item: http://repository.aaup.edu/jspui/handle/123456789/115
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dc.contributor.authorhisham qrareya-
dc.contributor.authorstefano protti, $Other$Other-
dc.contributor.authormaurizio fagnoni., $Other$Other-
dc.date.accessioned2020-01-10T09:10:32Z-
dc.date.available2020-01-10T09:10:32Z-
dc.date.issued2014-
dc.identifier.urihttp://repository.aaup.edu/jspui/handle/123456789/115-
dc.description.abstractSome oxygen-bonded substituents were investigated as leaving groups in photoinduced ArSN1 reactions. Irradiation of aryl imidazylates and of the corresponding imidazolium salts mainly caused homolysis of the ArO?S bond. However, previously unexplored tri?uoroethoxy aryl sulfates were found to undergo e?cient metal-free arylation. The sulfates were conveniently generated in situ by dissolving the corresponding imidazolium salts in basic 2,2,2-tri?uoroethanol.en_US
dc.publisherJournal of Organic Chemistry (JOC).en_US
dc.subjectArSN1 reactionen_US
dc.subjectmetal-free arylation.en_US
dc.titleAryl imidazylates and aryl sulfates. Novel electrophiles in metal-free ArSN1 reactionsen_US
dc.typeArticleen_US
Appears in Collections:Faculty & Staff Scientific Research publications

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