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Title: Kinetics of Oxidation of Some Fluoroquinolones by Hexacyanoferrate(III) in Alkaline Medium
Authors: nizam diab
ibrahim abu-shqair, $Other$Palestinian
mohammad al-subu, $Other$Palestinian
radi salim, $Other$Palestinian
Keywords: F luoroquinolones
P otassium hexacyanoferrate(III)
Osmium tetroxide
Issue Date: 2013
Publisher: International Journal of Chemistry
Abstract: Kinetics of osmium tetroxide catalyzed-oxidation of the studiedfluoroquinolones by potassium hexacyanoferrate(III) in alkaline mediumwere studied. The rate was found to be independent on the concentrationof hexacyanoferrate(III), and first order with respect to bothfluoroquinolone and OsO4. An empirical rate law was derived for thereaction, and the effect of various variables on the rate of reaction wasstudied. Thermodynamic parameters (Ea, ?H*, ?S*, ?G*) were alsocalculated.
Appears in Collections:Faculty & Staff Scientific Research publications

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