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Title: | Polarography of Pyridine 2 aldehyde 2 Pyridylhydrazone in solutionos of varying pH at a DME. Effect of surface Active substance |
Authors: | ali z. abu zuhri j. shalabi |
Issue Date: | 1985 |
Publisher: | Journal of the Chemical Society, Perkin Transactions 2 |
Abstract: | The polarographic behaviour of pyridine-2-carbaldehyde 2-pyridylhydrazone(PAPH) at a dropping-mercury electrode was studied in aqueous Britton–Robinson buffers containing 50% ethanol. The polarograms consist of one wave in the acidic and alkaline medium. Two electrons are consumed in the splitting of the N–N bond to give-2-aminopyridine and pyridine-2-carbaldehyde. The adsorption effects of cationic, anionic, and non-ionic surfactants on the polargraphic waves of PAPH have been investigated. The kinetic parameters for the electrode reaction at different pH values have been computed. |
URI: | http://repository.aaup.edu/jspui/handle/123456789/765 |
Appears in Collections: | Faculty & Staff Scientific Research publications |
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